Click here for AnswerPool.com Home page




Google

    AnswerPool.com  Hop To Forum Categories  Science  Hop To Forums  Chemistry    Thermodynamics

Moderators: clarebear
Go
Post
Find
Notify
Tools
Reply
  
  Login/Join 
Picture of su_chem
Posted
"The formation of carbon monoxide is much favoured at higher temperature than formation of carbondioxide by direct union of carbon and oxygen" How can this be explained from thermodynamic point of view?
 
Posts: 30 | Location: kolkata, India | Registered: 08-14-06Reply With QuoteEdit or Delete MessageReport This Post
Picture of rcck81
Posted Hide Post
If you need some answer, I would suggest that perhaps because the bond length of the CO is about 3% shorter than CO2, and the bond energy is about 2% higher that CO2 bonds are more easily broken. This being the case and all else being equal, CO will be the favored product of C2+O2
 
Posts: 7 | Location: Texas | Registered: 10-06-06Reply With QuoteEdit or Delete MessageReport This Post
Picture of su_chem
Posted Hide Post
According to your views CO is the favoured product of direct union of C and O as the bond energy of CO is higher than that of CO2.But the reason why it is favoured at higher temperature is not uderstood by your explanation.
 
Posts: 30 | Location: kolkata, India | Registered: 08-14-06Reply With QuoteEdit or Delete MessageReport This Post
Picture of dk_ch
Posted Hide Post
C(s) + O2(g) = CO2 - 389kJ/mole
C(s) + 0.5O2(g) = CO - 110kJ/mole
In the first reaction there is no volume change
but in the second reaction the volume of the product is doubled that of reactants. So the change in entropy (dS) in first case is small but large in case of second reaction. Hence the free energy change (dG) [calculated according to equation-dG = dH - TdS]for the first reaction remains more or less constant with increase in temperaure in case of formation of CO2. But in case of second reaction the free energy change (dG) becmes more and more negative above 983K as T increases as evident from Eningham diagram. So the formation of CO will be favoured at higher temperature as the dG becoming more and more negative with increase of temperature.
 
Posts: 14 | Location: kolkata | Registered: 08-30-06Reply With QuoteEdit or Delete MessageReport This Post
 Previous Topic | Next Topic powered by eve community  
 

    AnswerPool.com  Hop To Forum Categories  Science  Hop To Forums  Chemistry    Thermodynamics

© 2002-2008 AnswerPool.com



Visit DiscussionPool.com!