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C(s) + O2(g) = CO2 - 389kJ/mole C(s) + 0.5O2(g) = CO - 110kJ/mole In the first reaction there is no volume change but in the second reaction the volume of the product is doubled that of reactants. So the change in entropy (dS) in first case is small but large in case of second reaction. Hence the free energy change (dG) [calculated according to equation-dG = dH - TdS]for the first reaction remains more or less constant with increase in temperaure in case of formation of CO2. But in case of second reaction the free energy change (dG) becmes more and more negative above 983K as T increases as evident from Eningham diagram. So the formation of CO will be favoured at higher temperature as the dG becoming more and more negative with increase of temperature.
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| Posts: 22 | Location: kolkata | Registered: 08-30-06 |    |
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