Platinum Enthusiast
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A little over 53 degrees.
Let's say the film occupies the entire inside of the cube's rear face, with the pinhole centered in the front face.
The angle made by pinhole, center of film, and midpoint of one side of the film is arctan(1/2), about 26.5°, so the total subtended angle across is twice that, 53.1+°. The angle across the diagonal of the film will be 2*arctan(1/√2) = 70.5+°.
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